But the L'Oreal ambassador did her best impression of Angelina Jolie, by awkwardly sticking out her leg from under her pale pink dress from Atelier Versace's Fall 2012 collection.
But her perfect pins weren't the only thing on display, for Doutzen, 28, also revealed her chest thanks to the plunging neckline of her dress
The L'Oreal Paris model wore matching metallic sandals with the halterneck dress, but went without jewellery, letting the sequins do the dazzling.
Her blonde hair was styled into laid back waves, with her simple make-up look equally pared down, with just some black eye-liner to set off her eyes.
The mother-of-one appeared on the red carpet for the screening of Le Passé (The Pass) on Friday night.
The film stars Bérénice Bejo, Tahar Rahim and Ali Mosaffa, and follows the story of an Iranian man who deserts his French wife and two children to return to his homeland.
BUt when his wife starts a new relationship and files for divorce, the husband realises the gravity of his decision.
Asghar Farhadi's latest drama is up for the Pale D'or at the 66th Annual Cannes Film Festival.
It will be considered for the top prize by the jury led by Steven Spielberg.
But Doutzen hasn't just arrived into Cannes to watch some critically acclaimed cinema.
Her fellow L'Oreal ambassadors, American actress Eva Longoria, American athlete and model Aimee Mullins and French actress Leila Bekhti joined her at the event which is each year sponsored by the French beauty brand.
Source : dailymail
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